Science Common Sense


1733 - What is the relationship between electron pairs in the valence shell and the shape of molecules

Imagine you're playing with balloons. The balloons are like electron pairs in the valence shell of an atom. When you have different numbers of balloons (electron pairs) around a central point (the atom), they want to get as far away from each other as possible.

Here's how it works:

  1. 2 electron pairs: They move apart to form a straight line, making a 'linear' shape.
  2. 3 electron pairs: They arrange themselves in a triangular shape to get as far apart as possible, making a 'trigonal planar' shape.
  3. 4 electron pairs: They form a tetrahedron (like a triangular pyramid), making a 'tetrahedral' shape.
  4. 5 electron pairs: They form a square pyramid (or trigonal bipyramid), making a 'trigonal bipyramidal' shape.
  5. 6 electron pairs: They arrange themselves in an octahedral shape, making an 'octahedral' shape.

The electron pairs try to get as far away from each other as possible because they have the same charge and like to be separate. This is known as the VSEPR (Valence Shell Electron Pair Repulsion) model.

So, in simple words, the number of electron pairs in the valence shell of an atom determines the shape of the molecule by pushing them around to get as far apart as possible.